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Prince Felipe Antonio de Bourbon of Spain (maid. name Duke of Calabria)
1747 - 1777 (30 years)
| Marie Josepha Antoinetta de Bourbon of Spain (maid. name Princess) | |
 1742 - 1742 (0 years) |
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| Maria Isabel de Bourbon of Spain (maid. name Princess) | |
| 1743 - 1749 (5 years) |
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| Maria Josefa de Bourbon of Spain | |
| 1744 - 1801 (57 years) |
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| Maria Luisa de Bourbon of Spain (maid. name Holy Roman Empress) | |
| 1745 - 1792 (46 years) |
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| Prince Felipe Antonio de Bourbon of Spain (maid. name Duke of Calabria) | |
| 1747 - 1777 (30 years) |
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| Charles IV ( King of Spain) de Bourbon | |
| 1748 - 1819 (70 years) |
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| Maria Teresa de Bourbon of Spain (maid. name Princess) | |
| 1749 - 1750 (0 years) |
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| Ferdinand I de Bourbon of Naples and Sicily (maid. name King of the Two Sicilies) | |
| 1751 - 1825 (73 years) |
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| Gabriel Antonio Francisco de Bourbon of Spain (maid. name Infante) | |
| 1752 - 1788 (36 years) |
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| Maria Ana de Bourbon of Spain (maid. name Princess) | |
| 1754 - 1755 (0 years) |
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| Antonio Pascual de Bourbon of Spain (maid. name Infante) | |
| 1755 - 1817 (61 years) |
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| Francisco Javier de Bourbon of Spain | |
| 1757 - 1771 (14 years) |
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| Maria Amalia Wettin of Saxony | |
| 1724 - 1760 (35 years) |
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| Charles III King of * Spain | |
| 1716 - 1788 (72 years) |
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