| Children |
| | 1. George Henry Baron Scott Scott, b. 02 Jan 1798, Dalkeith, Midlothian, Scotland |
| + | 2. Charlotte Albina Montagu-Scott (maid. name Lady), b. 16 Jul 1799, Dalkeith, Midlothian, Scotland |
| | 3. Isabella Mary Montagu Douglas-Scott (maid. name Lady), b. 24 Oct 1800, Dalkeith House, Dalkeith, Midlothian, Scotland |
| + | 4. Walter Francis (5th Duke of Buccleuch) Montagu Douglas Scott, b. 25 Nov 1806, Dalkeith House, Midlothian |
| | 5. John Douglas Montague-Scott, b. 13 Jul 1809 |
| | 6. Margaret Harriet Montagu-Scott (maid. name Lady), b. 12 Jun 1811, Dalkeith, Midlothian, Scotland |
| + | 7. Harriet Janet Sarah Montagu-Scott (maid. name Lady), b. 13 Aug 1814, Dalkeith House, Dalkeith, Midlothian, Scotland |
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